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This article lays out the PVE story mode use for each hero. This list pays NO heed whatsoever to Special Operations and PVP. It covers all released chapters of the PVE storyline, with their deploys and specific heroes needed to unlock Epic Bosses or Premium Missions.

For tips on the choice/use of heroes in PVP:
PvP Strategy

Each use of a hero is worth one (1) point. So say for example, Black Cat has one specific deploy but it is imperative to unlock an Epic Boss, thus counting as 2 points, 1/Deploy and 1/EB requirement.

So, in short, the column "Score" is the one that tells you the usefulness of recruiting an hero (deploy-wise) 6 Bar01 being most useful and blank Bar02 being heroes not involved in the main plotline.

The "Price" column was added only for you to know how much you'll have to pay to get them without the need of going to the actual Hero's page (thus saving time).

Hero usefulness based on number of deploys:

Who to recruit next?
Heroes Deploys Premium Epic Boss Req. SCORE PRICE
Infiltratoricon Black Widow 1x3, 3x5, 5x2, 6x5, 8x1 - 3x5 Bar01 Bar01 Bar01 Bar01 Bar01 Bar01 Default
Infiltratoricon Spider-man 3x5, 7x3, 9x5 Chapter 03 3x5, 7x3 Bar01 Bar01 Bar01 Bar01 Bar01 Bar01 90 Command point icon
Tacticianicon Hawkeye 1x2, 3x6, 5x6, 8x5, - 8x5 Bar01 Bar01 Bar01 Bar01 Bar01 Bar02 1 Command point icon
Bruisericon Thing 2x1, 7x6, 9x1, 9x4 - 9x4 Bar01 Bar01 Bar01 Bar01 Bar01 Bar02 33 Command point icon
Blastericon Human Torch 4x1, 6x1, 9x2 Chapter 07 - Bar01 Bar01 Bar01 Bar01 Bar02 Bar02 33 Command point icon
Infiltratoricon Invisible Woman 3x2, 7x6, 9x4 - 9x4 Bar01 Bar01 Bar01 Bar01 Bar02 Bar02 15 Command point icon
Scrappericon Luke Cage 2x4, 6x3 Chapter 10 6x3 Bar01 Bar01 Bar01 Bar01 Bar02 Bar02 23 Command point icon
Blastericon Storm 4x4, 6x6, 9x1 - 4x4 Bar01 Bar01 Bar01 Bar01 Bar02 Bar02 48 Command point icon
Scrappericon Wolverine 5x3, 7x2 Chapter 04 5x3 Bar01 Bar01 Bar01 Bar01 Bar02 Bar02 90 Command point icon
Scrappericon Daredevil 1x4, 6x5, 9x3 - - Bar01 Bar01 Bar01 Bar02 Bar02 Bar02 48 Command point icon
Blastericon Doctor Strange 4x5, 7x4 Chapter 09 - Bar01 Bar01 Bar01 Bar02 Bar02 Bar02 23 Command point icon
Bruisericon Hulk 4x2, 8x2 Chapter 01 - Bar01 Bar01 Bar01 Bar02 Bar02 Bar02 90 Command point icon
Scrappericon Iron Fist 3x1, 5x4, 7x5 - - Bar01 Bar01 Bar01 Bar02 Bar02 Bar02 15 Command point icon
Blastericon Iron Man 3x3, 5x6 Chapter 02 - Bar01 Bar01 Bar01 Bar02 Bar02 Bar02 Default
Tacticianicon Mr. Fantastic 4x3, 7x1, 9x2 - - Bar01 Bar01 Bar01 Bar02 Bar02 Bar02 33 Command point icon
Blastericon Phoenix 4x6, 6x2 Chapter 06 - Bar01 Bar01 Bar01 Bar02 Bar02 Bar02 48 Command point icon
Bruisericon Thor 5x1, 6x4, 7x4 Chapter 08 - Bar01 Bar01 Bar01 Bar02 Bar02 Bar02 90 Command point icon
Infiltratoricon Black Cat 2x3 - 2x3 Bar01 Bar01 Bar02 Bar02 Bar02 Bar02 23 Command point icon
Tacticianicon Captain America 5x2, 8x4 Chapter 11 (not yet released) - Bar01 Bar01 Bar02 Bar02 Bar02 Bar02 90 Command point icon
Tacticianicon Cyclops 2x5, 8x3, - - Bar01 Bar01 Bar02 Bar02 Bar02 Bar02 15 Command point icon
Infiltratoricon Kitty Pride 5x4, 8x4 - - Bar01 Bar01 Bar02 Bar02 Bar02 Bar02 33 Command point icon
Infiltratoricon Nightcrawler 2x2, 5x5 - - Bar01 Bar01 Bar02 Bar02 Bar02 Bar02 48 Command point icon
Generalisticon Rogue 9x4 - 9x4 Bar01 Bar01 Bar02 Bar02 Bar02 Bar02 90 Command point icon
Bruisericon She-Hulk 1x6, 6x2 - - Bar01 Bar01 Bar02 Bar02 Bar02 Bar02 15 Command point icon
Scrappericon Sif 1x5, 8x6 - - Bar01 Bar01 Bar02 Bar02 Bar02 Bar02 23 Command point icon
Tacticianicon War Machine 2x6 Chapter 05 - Bar01 Bar01 Bar02 Bar02 Bar02 Bar02 48 Command point icon
Bruisericon Colossus 3x4 - - Bar01 Bar02 Bar02 Bar02 Bar02 Bar02 23 Command point icon
Blastericon Ms. Marvel 9x6 - - Bar01 Bar02 Bar02 Bar02 Bar02 Bar02 15 Command point icon
Scrappericon Spider-Woman 7x1, 10x4 - 10x4 Bar01 Bar01 Bar01 Bar02 Bar02 Bar02 33 Command point icon
Generalisticon Beast None - - Bar02 Bar02 Bar02 Bar02 Bar02 Bar02 90 Command point icon
Tacticianicon Black Panther None - - Bar02 Bar02 Bar02 Bar02 Bar02 Bar02 90 Command point icon
Blastericon Cable None - - Bar02 Bar02 Bar02 Bar02 Bar02 Bar02 Season 2 Adamantium League or (?) Command point icon
Scrappericon Deadpool None - - Bar02 Bar02 Bar02 Bar02 Bar02 Bar02 Season 1 Adamantium League or 90/112/135 Command point icon
Tacticianicon Emma Frost None - - Bar02 Bar02 Bar02 Bar02 Bar02 Bar02 SpecOps #2
Infiltratoricon Gambit None - - Bar02 Bar02 Bar02 Bar02 Bar02 Bar02 90 Command point icon
Scrappericon Ghost Rider None - - Bar02 Bar02 Bar02 Bar02 Bar02 Bar02 SpecOps #4
Bruisericon Hercules None - - Bar02 Bar02 Bar02 Bar02 Bar02 Bar02 90 Command point icon
Scrappericon Magik None - - Bar02 Bar02 Bar02 Bar02 Bar02 Bar02 SpecOps #3
Generalisticon Mockingbird None - - Bar02 Bar02 Bar02 Bar02 Bar02 Bar02 SpecOps #1 or 200 Command point icon
Scrappericon Quicksilver None - - Bar02 Bar02 Bar02 Bar02 Bar02 Bar02 48 Command point icon
Blastericon Scarlet Witch None - - Bar02 Bar02 Bar02 Bar02 Bar02 Bar02 90 Command point icon
Infiltratoricon Tigra None - - Bar02 Bar02 Bar02 Bar02 Bar02 Bar02 90 Command point icon
Bruisericon Valkyrie None - - Bar02 Bar02 Bar02 Bar02 Bar02 Bar02 SpecOps #5 or 200 Command point icon
Infiltratoricon Psylocke None - - Season 3 Adamantium League or (?) Command point icon


V  UNDER CONSTRUCTION  V   This is how it'll look when the edit's over. Ignore it for now.

List

Name Deploys Premium Epic Boss Req Score Price Unique Drops
Black Widow Infiltratoricon  1x3, 3x5, 5x2, 6x5, 8x1 None None Bar01 Bar01 Bar01 Bar01 Bar01 Bar01 Default None
Hawkeye Tacticianicon  1x2, 3x6, 5x6, 8x5, None 8x5 Bar01 Bar01 Bar01 Bar01 Bar01 Bar02 90 Command point icon (1) Possessed Pistol
Black Panther Tacticianicon  None None None Bar02 Bar02 Bar02 Bar02 Bar02 Bar02 {X} None
Ms. Marvel Blastericon  9x6 None None Bar01 Bar02 Bar02 Bar02 Bar02 Bar02 15 Command point icon None
Valkyrie Bruisericon  None None None Bar02 Bar02 Bar02 Bar02 Bar02 Bar02 SpecOps #5 or 200 Command point icon None
 Hulk  Bruisericon  4x2, 8x2 Chapter 01 None Bar01 Bar01 Bar01 Bar02 Bar02 Bar02 90 Command point icon

(2) Gamma Gadget Gamma Booster

The Exsanguinator 15% {X} One Enemy {X} {X} --
Witch-Hunter 15% {X} All Enemies {X} {X} --
Chain Tonfa 10% {X} One Enemy {X} {X} --
Scroll of Melsalam 15% {X} All Allies -- -- 3 Rounds
Rocket Pistol 20% {X} One Enemy {X} {X} 1 Round
The Pawn 15% {X} Self {X} {X} --
The Knight 20% {X} One Enemy {X} {X} -
Traumatic Post 20% {X} One Enemy {X} {X} -
Techno-Organic Endoskeleton 20% {X} One Enemy {X} 100% --
Transcranial Stimulator 20% {X} One Enemy {X} {X} --
Crystal Shiv 20% {X} One Enemy {X} {X} --
Bonechiller 25% {X} All Enemies {X} {X} -
Item 47 20% {X} One Enemy {X} {X} --
Loki's Sceptre 20% {X} One Enemy {X} {X} --
Anklebiter 15% {X} One Enemy {X} {X} -
Soulfire Blade ? {X} One Enemy {X} 94% /
22%
-
Hex Wand 20% {X} One Enemy {X} {X} 3 Rounds
Blade of the Guardian 20% {X} One Enemy {X} {X} -
Lightning Rod 25% {X} One Enemy {X} {X} -
Widow's Scorn 25% {X} One Enemy {X} {X} -
Blade of the Corruptor 20% {X} One Enemy {X} {X} -
Barrowguard 20% {X} One Enemy {X} {X} -
Warbringer Axe 22% {X} One Enemy {X} {X} -
Cat's Claw 20% {X} One Enemy {X} {X} -
Ironstar 22% {X} All Enemies 300 - 360 100% / 19% -

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