Well let's see if any of thus holds up 10 months down the road....
New LE alt costume for Captain America
LE costume for Falcon (who I predict will be released prior to this)
Villains: Crossbones, Batroc, and Winter Soldier
Spec Ops reward hero: Winter Soldier
Lockbox hero: Crossbones (he was one of Luke's Thunderbolts)
The plot will loosely follow the plot of the movie, chapter 1 may involve a flashback mission to allow Winter Soldier as a hero for the team-up tasks. Crossbones and Batroc will definately be villains.
Release: April 2014 as a tie in to Captain America: The Winter Soldier
I wont make any speculations beyond the basic facts stated above, see ya all 10 months from now to see if this holds up.