Chapter 3 - Enter Doom
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"Former enemies and rivals begin to band together as New York's villains realize the potential of Iso-8. And the more you learn about who's really pulling the strings, the more all signs point to Latveria..."
— Chapter Briefing
Mission 1 - Sacred Ground 
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- 9,000 points 
"St. Patrick's cathedral is under assault by Servo Guards, typically Doctor Doom's robotic soldiers.Work with Luke Cage to find out what's behind the attack."
— Mission Preview
Unlock Requirements:
Recruit 6 Heroes
Complete 1 Star Mastery in Chapter 2 - Mission 5
Acquire a total of 15 Mastery Stars
Location: St. Patrick's Cathedral
Team-Up: Luke Cage
Battles
Low: x3
Medium: x1
High: x2
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Mini-Boss
Minimum Cleared: 1
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Team-Up: Luke Cage
Boss
Minimum Cleared: 5
Team-Up: Luke Cage
Boss Drops: Cryo-Tonfa, Assault Shotgun
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Boss + Mini-Boss
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Deploy Missions
Requirement: Iron Fist
Duration: 2 Battles
Requirement: Any Scrapper
Duration: 1 Battle
Requirement: Any Hero
Duration: 2 Battles
Mission 2 - Brooklyn Bridge is Falling Down Edit
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"Doctor Doom has to wait as the Maggia wreak havoc at the Brooklyn Bridge. The Fantastic Four's Thing is on hand to help shut down these Iso-8 enhanced mobsters."
— Mission Preview
Unlock Requirements:
Complete 1 Star Mastery in Chapter 3 - Mission 1
Location: Brooklyn Bridge
Team-Up: Thing
Battles
Low: x1
Medium: x3
High: x2
Mini-Boss
Minimum Cleared: 2
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Team-Up: Thing
Boss
Minimum Cleared: 3
Team-Up: Thing
Boss Drops: Tidal Fist, NF3000
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Boss + Mini-Boss
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Deploy Missions
Requirement: Any Scrapper
Duration: 3 Battles
Requirement: Invisible Woman
Duration: 2 Battles
Requirement: Any Hero
Duration: 1 Battles
Mission 3 - RAID-ical Resolution Edit
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"The United Nations is under attack by R.A.I.D.. Heads of State are in danger and S.H.I.E.L.D. has a new priority."
— Mission Preview
Unlock Requirements:
Complete 1 Star Mastery in Chapter 3 - Mission 2
Location: UN Building
Team-Up: War Machine
Battles
Low: x1
Medium: x2
High: x3
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Mini-Boss
Minimum Cleared: 3
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Team-Up: War Machine (optional)
Boss
Minimum Cleared: 4
Team-Up: War Machine
Boss Drops: D.A.R.S. Suppressor, S.A. "Siege"
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Boss + Mini-Boss
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Deploy Missions
Requirement: Any Hero
Duration: 1 Battle
Requirement: Any Bruiser
Duration: 1 Battle
Requirement: Iron Man
Duration: 3 Battles
Mission 4 - Odd Bedfellows Edit
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"Sentinels have been spotted in Times Square, Brotherhood Mutants have been seen in combat. Time to get in the middle of this."
— Mission Preview
Unlock Requirements:
Complete 1 Star Mastery in Chapter 3 - Mission 3
Location: Times Square
Team-Up: Kitty Pryde
Battles
Low: x2
Medium: x2
High: x2
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Mini-Boss
Minimum Cleared: 2
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Team-Up: Kitty Pryde
Boss
Minimum Cleared: 5
Team-Up: Kitty Pryde
Boss Drops: Offensive Accelerator, Fang-L13
Challenge Boss Drops: Custom Foley's Heart Tickler
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Boss + Mini-Boss
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Deploy Missions
Requirement: Colossus
Duration: 2 Battles
Requirement: Any Infiltrator
Duration: 1 Battle
Requirement: Any Hero
Duration: 1 Battle
Requirement: Any Hero
Duration: 2 Battles
Mission 5 - Three Strikes Edit
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"A mission deployment to Ryker's Island leads to trouble at Yankee Stadium."
— Mission Preview
Unlock Requirements:
Complete 1 Star Mastery in Chapter 3 - Mission 4
Location: Yankee Stadium
Team-Up: Hawkeye
Battles
Low: x2
Medium: x2
High: x2
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Mini-Boss
Minimum Cleared: None
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Team-Up: Hawkeye (Optional)
Minimum Cleared: 2
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Team-Up: Hawkeye (Optional)
Boss
Minimum Cleared: 6
Team-Up: Hawkeye
Boss Drops: D.A.R.S. Suppressor, Curative Reach
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Boss + Mini-Boss
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Deploy Missions
Requirement: Black Widow
Duration: 1 Battle
Requirement: Any Blaster
Duration: 1 Battle
Requirement: Any Tactician
Duration: 2 Battles
Requirement: Spider-Man
Duration: 2 Battles
Epic Boss
Must finish ALL battles and deploys before the Epic Boss will appear
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Team-Up: Hawkeye (Optional)
Epic Boss Drops: The Doombringer
Premium Mission: Cephalocarrier Edit
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"Spider-Man's arch-nemesis Dr. Octopus has taken over the U.S.S. Intrepid. How about if you help the friendly neighborhood hero put Ock on ice?"
— Mission Preview
Unlock Requirements: Recruit Spider-Man
Location: USS Intrepid
Team-Up: Spider-Man
Note: Mission difficulty scales to players' agent level
Battles
Low: x3
Medium: x2
High: x2
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Mini-Boss
Minimum Cleared: 5
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Team-Up: Spider-Man (Optional)
Minimum Cleared: 5
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Team-Up: Spider-Man (Optional)
Boss
Minimum Cleared: 8
Team-Up: Spider-Man
Boss Drops: Web Blaster, Galvanic Arm
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Boss + Mini-Boss
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Deploy Missions
Requirement: Hawkeye
Duration: 2 Battles
Requirement: Any Scrapper
Duration: 1 Battle
Requirement: Any Hero
Duration: 2 Battles
Requirement: Spider-Woman
Duration: 1 Battle
| v · e | |||
|---|---|---|---|
| 1. The Hydra's Tail 2. Class is in Session 3. HAIL HYDRA! 4. Designed Only for Killing 5. O Brother, Where Art Thou? Premium Mission: Extra Large | 
| 1. In the Family 2. The Sound of Feathers Ruffling 3. Step into the Shadows 4. Mean People 5. Mutate or Die Premium Mission: Ulterior Motive |
| Dialogues | Dialogues | ||
|
| 1. Sacred Ground 2. Brooklyn Bridge is Falling Down 3. RAID-ical Resolution 4. Odd Bedfellows 5. Three Strikes Premium Mission: Cephalocarrier | 
| 1. Jailbreak 2. Center Point 3. Hydrophobia 4. Unexpected Guest 5. Command Performance Premium Mission: Tooth and Claw |
| Dialogues | Dialogues | ||
| 1. An Early Frost 2. Taking AIM 3. Chemistry Set 4. Desecration 5. City of Stone Premium Mission: Hydra Assemble! | 
| 1. Underworld Masquerade 2. I Predict a Riot 3. Tentacular 4. Mutants Marching 5. Magic Hand Premium Mission: Jailhouse Rock |
| Dialogues | Dialogues | ||
| 1. Anticipation 2. Taking It to the Streets 3. Head Shot 4. Deceiver and Destroyer 5. Chaos Reigns Premium Mission: A Whole New U | 
| 1. Enemies Hand in Hand 2. Congressional Action 3. Grand Experiment 4. Quis Custodiet 5. Regeneration Premium Mission: Bring the Thunder |
| Dialogues | Dialogues | ||
| 1. The Boss is Back 2. Mutatis Mutandis 3. Hand and Fist 4. Weird Science 5. Criminal Minds Premium Mission: Darkness Rising | 
| 1. U-Foe Sighting 2. Power Play 3. Stormy Weather 4. Grinning Skull 5. The Syndicate Premium Mission: Der Rote Schadel Lebt Noch |
| Dialogues | Dialogues | ||
| 1. Mutants Take Manhattan 2. HYDRA for Humans! 3. Enter the Circle 4. Underground Resistance 5. Mutation Zone Premium Mission: Breaking the Syndicate | 
| 1. Lokasenna 2. Ouroboros 3. Under the Hood 4. Technocrats 5. Feeding Frenzy Premium Mission: Doom's Day |
| Dialogues | |||
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